Paper-II

Section A
1. Answer any four of the following:
a. Find the first-order rate constant for the disappearance of A in the gaseous reaction 2A holding the pressure constant, the volume of the reaction mixture starting with 80 per cent A decreases by 20 per cent in 3 mm
b. A solution contains 50 per cent benzene, 30 per cent toluene and 20% xylene by weight at 100° C. The vapours are in contact with the solutions. Calculate total pressure and mole per cent composition of liquid and vapour:
c. Show that the internal energy of an ideal gas is a function of temperature only
d. For adiabatic batch reactor, derive an expression to determine the time required to achieve a desired conversion
e. Define Bubble point and Dew point. Explain in detail how to calculate bubble point or dew point of given binary mixture
2. The elementary reaction. A B R S is effected in a set up consisting of a mixed reactor into which two reactant solutions are introduced followed by a PFR. A large enough of excess of B is used so that the reaction is first order w. r. t. A. It is proposed to reverse the order of two units. How does this change affect the conversion
3. A high purity limestone is burnt in a lime kiln which is fired externally with a coal containing 75.5 per cent 5.5 per cent 1.6 per cent 1.1 per cent 7.6 per cent and rest ash. The stack gas analysis is 20.2% CO2, 7.1% O2 and rest N2, Calculate-
a. kg limestone burnt/kg of coal
b. excess air used for combustion
4. One mole of an ideal gas initially at P1 and T1 is compressed reversibly and adiabatically till the pressure is P2 and then it is cooled at constant volume to the initial pressure, finally the gas is restored to the initial state through an isobaric process. Calculate the work done by the process

Section B
5. Answer any four of the following:
a. Define depreciation. What are the different methods for determining depriciation? Explain the method, sum of the years digit method
b. Explain briefly the factors to be considered for the location of a chemical plant
c. Describe the manufacture of caustic soda by either diaphragm or mercury cell process. Discuss the pollution aspects of this industry
d. Explain briefly the pollutants emitted from a tanning industry
e. Explain the cracking and polymerisation of petroleum fractions
6. Answer the following questions
a. Explain the break-even analysis and its equation
b. A Project can produce 12000 units per year at 100 per cent capacity. The variable cost per unit is Rs. 3 at 100 per cent capacity. Fixed costs are Rs. 10, 000 per year. Find the break-even point if the selling price is Rs. 5/unit. Now the manufacturer finds that he can sell only 80% at Rs. 5/unit. How much should he charge for additional units if he brings production upto 100 per cent capacity and increases profits after taxes by an additional amount of Rs. 000?
Use tax rate for the above problem 52 per cent.
7. Answer the following questions
a. Describe the process with neat flow sheet of the manufacture of ethyl alcohol
b. Discuss the applications of following products:
1. Enamel paint
2. Rancidity.
8. Answer the following questions
a. Discuss the methods possible for preventing various industrial hazards
b. Explain primary treatment method of waste-water treatment