N A L A N D A O P E N U N I V E R S I T Y
M.Sc. Chemistry, Part-II
PAPER-X
(Advance Chemical Dynamics)
Annual Examination, 2017
Time 3 Hours. Full Marks 80
Answer any FIVE Questions.
All questions carry equal marks.
1. Discuss the effect of ionic strength and dielectric constant of the medium on the rate constant
of the reaction.
2. What is the activation energy role in explaining the catalysis reaction.
Derive Bronsted Catalysis relation. Explain oscillatory reaction.
3. What is faradaic and non faradaic process Explain Stoichiometric number and transfer
co-efficients
4. Answer the following
General Mechanism of Catalystic reaction.
Bronsted Catalyssis reaction.
5. Explain the kinectics of reaction in liquid and gas phase. What is diffusion controlled reaction
6. Discuss the NMR method for study of fast reaction.
7. Explain Corrosion Describe the theories of Corrosion. How a metal can be protected from
corrosion.
8. What is Kinetic salt effect Describe the Bronsted Bjerrum equation.
9. What do you understand by the dynamics of reaction What is mechanism of activation
Discuss potential energy surfaces.
10. Write notes on the following
Stoichiometric number and transfer co-efficients.
Oscillatory reaction.