Exam Details

Subject inorganic chemistry — ii
Paper paper 1
Exam / Course m.sc
Department
Organization rayalaseema university
Position
Exam Date May, 2018
City, State andhra pradesh, kurnool


Question Paper

M.Sc. DEGREE EXAMINATION, APRIL/MAY 2018.
Second Semester
Organic Chemistry/Natural Products
Paper I INORGANIC CHEMISTRY — II
2 20121 A
Time 3 Hours Max. Marks 70
PART — A
Answer any FIVE questions. 6 30 Marks)
1. Write about Marcus theory.
2. Explain Anation reactions.
3. Explain calculation of Microstates for d2 configural.
4. Discuss d-orbital splitting in tetrahedral complexes.
5. Define Anionic and Hydrido clusters.
6. What is Quadropole bond?
7. Explain Antagonism and Synergism.
8. Discuss the structure of heme.
PART — B
Answer ALL questions. 10 40 Marks)
9. Explain acid catalysis and discuss the factors affecting acid hydrolysis.
Or
10. Explain electron transfer reaction and discuss outer sphere mechanism.
11. Describe J-J coupling scheme Charge transfer spectra for complexes.
Or
splitting pattern of d-orbital.

13. Give the tetragonal prismatic and antiprismatic structures.
Or
14. Discuss
Low neucleanty clusters
Octahedral metal halide
Chalcogenide clusters.
15. Explain structure and functional aspects of haemoglobin.
Or
16. Discuss
Structure to chlorophyll.
Z-scheme involving PSI and PSII.
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